A number of resources for learning to use GROMACS are available.
You can find a step-by-step demo and several nice examples in the share/tutor subdirectory of your GROMACS installation.
You can either browse around there on your own, or continue to our Online Reference Manual. That page is also available in your GROMACS installation directory under share/html/online/getting_started.html, so you can use it offline too!